Li3V2(PO4)3/Li3PO4 Cathode Materials for Li-Ion Batteries: Synthesis and Characterization

نویسندگان

چکیده

Li3V2(PO4)3/Li3PO4 (LVPO/LPO) composites as cathodes for Li-ion batteries were synthesized by the hydrothermal method and subsequently annealed in an Ar atmosphere. The effect of Li3PO4 content on crystal structure, morphology related magnetic electrochemical properties composites, containing 7.5 wt% 14 (LVPO/LPO-7.5 LVPO/LPO-14) was investigated. microstructure obtained characterized X-ray diffraction (XRD) scanning electron microscopy (SEM); investigations performed using spin resonance galvanostatic methods, respectively. It shown that exhibit a high discharge capacity, good cycle performance (105 120 mAh g−1 200th at 1C LVPO/LPO-7.5 LVPO/LPO-14, respectively), insignificant changes surface after 200 lithiation/delithiation cycles. Our results demonstrate increase led to decrease Li stoichiometry inhomogeneity Li3V2(PO4)3 phase; thus, improvement LVPO/LPO due incorporation can be attributed their chemical inhomogeneity.

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ژورنال

عنوان ژورنال: Magnetochemistry

سال: 2022

ISSN: ['2312-7481']

DOI: https://doi.org/10.3390/magnetochemistry8090105